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Synthesis, proton NMR stereochemical study and diels-alder reaction of (E)-7-arylidene-2H,6H-naphtho[1,8-bc]furan-2,6-diones

✍ Scribed by Zouhair Bouaziz; Houda Fillion; Henri Pinatel


Book ID
112130542
Publisher
Journal of Heterocyclic Chemistry
Year
1993
Tongue
English
Weight
258 KB
Volume
30
Category
Article
ISSN
0022-152X

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The reaction of 2,6-diarylidenecyclohexanones with hydrazine hydrate in glacial acetic acid resulted in the formation of diastereomers of (E)-2-acetyl-3-aryl-7-arylidene-3,3a,4,5,6,7-hexahydroindazoles. The relative conÐgurations of these diastereomers were unambiguously assigned using 1H and 13C NM