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Synthesis, properties, and X-ray structure of [Cu(dpa)Cl2] (dpa = di-(2-picolyl)amine)

✍ Scribed by Ki-Young Choi; Haiil Ryu; Nack-Do Sung; Mancheol Suh


Book ID
111569493
Publisher
Springer
Year
2003
Tongue
English
Weight
47 KB
Volume
33
Category
Article
ISSN
1572-8854

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The preparation, crystal structures and magnetic properties of two copper(II) complexes with di-2-pyridylamine (dpa) as end-cap ligand and azide (1) and cyanate (2) as bridging groups, [Cu(dpa)(N 3 ) 2 ] n (1) and [Cu 2 (dpa) 2 (NCO) 4 ] (2), are reported. Compound 1 consists of uniform chains of co

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## Abstract The neutral, monocationic, and dicationic linear trinuclear ruthenium compounds [Ru~3~(dpa)~4~(CN)~2~], [Ru~3~(dpa)~4~(CN)~2~][BF~4~], [Ru~3~(dpa)~4~Cl~2~][BF~4~], and [Ru~3~(dpa)~4~Cl~2~][BF~4~]~2~ (dpa=the anion of dipyridylamine) have been synthesized and characterized by various spe