Synthesis and characterization of titanium and tantalum complexes with di(2-pyridyl)amine (dpa): Molecular structures of Cp*TaCl3(dpa) and Ti(NMe2)2(dpa)2
✍ Scribed by Rosa Fandos; Carolina Hernández; Antonio Otero; Ana Rodríguez; Maria José Ruiz
- Book ID
- 108188113
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 183 KB
- Volume
- 690
- Category
- Article
- ISSN
- 0022-328X
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The preparation, crystal structures and magnetic properties of two copper(II) complexes with di-2-pyridylamine (dpa) as end-cap ligand and azide (1) and cyanate (2) as bridging groups, [Cu(dpa)(N 3 ) 2 ] n (1) and [Cu 2 (dpa) 2 (NCO) 4 ] (2), are reported. Compound 1 consists of uniform chains of co
## Abstract The neutral, monocationic, and dicationic linear trinuclear ruthenium compounds [Ru~3~(dpa)~4~(CN)~2~], [Ru~3~(dpa)~4~(CN)~2~][BF~4~], [Ru~3~(dpa)~4~Cl~2~][BF~4~], and [Ru~3~(dpa)~4~Cl~2~][BF~4~]~2~ (dpa=the anion of dipyridylamine) have been synthesized and characterized by various spe