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Synthesis, Properties, and Hydroboration Activity of the Highly Electrophilic Borane Bis(pentafluorophenyl)borane, HB(C 6 F 5 ) 21

✍ Scribed by Parks, Daniel J.; Piers, Warren E.; Yap, Glenn P. A.


Book ID
126795084
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
161 KB
Volume
17
Category
Article
ISSN
0276-7333

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## Abstract The scope of the B(C~6~F~5~)~3~‐catalyzed hydrosilylation of (X)Ph–CH=O and (X)Ph–C(R)=O was expanded to include a large set of substitutents (X = H, __p__‐Me, __o__‐Me, __p__‐F, __o__‐F, __p__‐Cl, __p__‐Br, __p__‐NO~2~, __m__‐NO~2~, __p__‐Et; R = Me or CF~3~). Reactions proceed at room