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Synthesis of Cyclopentadienyl-, Indenyl-, and Fluorenylbis(pentafluorophenyl)boranes as Ligands in Titanium and Zirconium Half-Sandwich Complexes. The Crystal Structures of C 13 H 9 B(C 6 F 5 ) 2 · t -BuNH 2 , C 13 H 8 SiMe 3 B(C 6 F 5 ) 2 , and {η 5 -C 5 H 4 B(C 6 F 5 ) 2 }TiCl 3

✍ Scribed by Duchateau, Robbert; Lancaster, Simon J.; Thornton-Pett, Mark; Bochmann, Manfred

Book ID: 121395841
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 506 KB
Volume: 16
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om970433j

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## Abstract Both amido‐(cyclopentadienyl)boranes and bis(cyclopentadienyl)boranes of the types R~2~NB(C~__x__~H~__y__~) (NR′) and R~2~NB(C~__x__~H~__y__~)~2~ (R = alkyl, trimethylsilyl; R′ = Ph; C~__x__~H~__y__~ = C~5~H~5~ (cyclopentadienyl), C~9~H~7~ (indenyl), C~13~H~9~ (fluorenyl)) were recently