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Synthesis, Photophysics, Electrochemistry, Theoretical, and Transient Absorption Studies of Luminescent Copper(I) and Silver(I) Diynyl Complexes. X-ray Crystal Structures of [Cu 3 (μ-dppm) 3 (μ 3 -η 1 -C⋮CC⋮CPh) 2 ]PF 6 and [Cu 3 (μ-dppm) 3 (μ 3 -η 1 -C⋮CC⋮CH) 2 ]PF 6

✍ Scribed by Lo, Wing-Yin; Lam, Chi-Ho; Yam, Vivian Wing-Wah; Zhu, Nianyong; Cheung, Kung-Kai; Fathallah, Sofiane; Messaoudi, Sabri; Le Guennic, Boris; Kahlal, Samia; Halet, Jean-François


Book ID
127196762
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
370 KB
Volume
126
Category
Article
ISSN
0002-7863

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✍ Vivian Wing-Wah Yam; Chi-Ho Lam; Kung-Kai Cheung 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 132 KB

A luminescent bicapped trinuclear copper(I) acetylide complex, [Cu 3 (m-dppm) 3 (m 3 -h 1 -C C-benzo-15-crown-5) 2 ]PF 6 , has been synthesized and its photophysical properties studied. Sodium ion-binding by the crown ether cavity has been studied by electrospray ionization-mass spectrometry and emi