Synthesis, photophysical, and electrochemical properties of two polynuclear ruthenium(II) polypyridyl complexes containing diazafluorene
✍ Scribed by Feixiang Cheng; Jishu Chen; Fan Wang; Ning Tang; Longhai Chen
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 361 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0340-4285
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Four novel Ru(II) complexes [Ru(L) 2 amtp] 2+ [L = 2,2 0 -bipyridine (bpy, 1); 4,4 0 -dimethyl-2,2 0 -bipyridine (dmb, 2); 1,10-phenanthroline (phen, 3); 2,9-dimethyl-1,10-phenanthroline (dmp, 4); amtp = 3-amino-1,2,4-triazino[5,6-f]1,10-phenanthroline] have been synthesized and characterized by ele
## Abstract The synthesis of a number of new 2,2′‐bipyridine ligands functionalized with bulky amino side groups is reported. Three homoleptic polypyridyl ruthenium (II) complexes, [Ru(L)~3~]^2+^ 2(PF~6~^−^), where L is 4,4′‐dioctylaminomethyl‐2,2′‐bipyridine (Ru4a), 4,4′‐didodecylaminomethyl‐2,2′‐
## Abstract [2]Rotaxanes based on the 1,2‐bis(pyridinium)ethane⊂[24]crown‐8 ether motif were prepared that contain a terminal terpyridine group for coordination to a transition‐metal ion. These rotaxane ligands were utilized in the preparation of a series of heteroleptic [Ru(terpy)(terpy–rotaxane)]