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Synthesis of γ,δ-Didehydrohomoglutamates by the Phosphine-Catalyzed γ-Addition Reaction to Acetylenic Esters

✍ Scribed by Alvarez-Ibarra, Carlos; Csákÿ, Aurelio G.; Gómez de la Oliva, Cristina

Book ID
126815700
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
115 KB
Volume
65
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Synthesis of γ,δ-Di
ChemInform Abstract: Synthesis of γ,δ-Didehydrohomoglutamates by the Phosphine-Catalyzed γ-Addition Reaction to Acetylenic Esters.
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g-Hydroxy-a,b-acetylenic esters containing three adjacent and structurally very different functional groups are very useful in the synthesis of highly functionalized organic molecules. [1, 2] This class of compound is normally prepared by treatment of an alkyl propiolate with nBuLi at À78 8C