✦ LIBER ✦

Synthesis of γ-Amino- and δ-Amino-Functionalised Ethers, Amines, or Silanes by Hydroaminomethylation of Heterofunctionalised Allylic Compounds

✍ Scribed by Thorsten Rische; Lars Bärfacker; Peter Eilbracht

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 296 KB
Volume: 1999
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(199903)1999:3<653::aid-ejoc653>3.0.co;2-r

No coin nor oath required. For personal study only.

✦ Synopsis

Heterofunctionalised allylic ethers 1, silanes 5, and amines 9 subsequent reductive amination to generate the corresponding functionalised secondary or tertiary amines. are hydroformylated in the presence of primary or secondary amines 2 to form the corresponding γ-amino-and δ-amino-This selective one-pot hydroaminomethylation procedure establishes access to γ-amino-and δ-amino-functionalised functionalised compounds.

The rhodium(I)-catalysed reaction sequence proceeds by aldehyde formation and ethers, amines or silanes with potential biological activity.

tertiary γ-amino-and δ-amino-functionalised ethers 3a؊f

Hydroformylation of allylsilanes hitherto has rarely been

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of γ-Amin

ChemInform Abstract: Synthesis of γ-Amino- and δ-Amino-Functionalized Ethers, Amines, or Silanes by Hydroaminomethylation of Heterofunctionalized Allylic Compounds.

✍ Thorsten Rische; Lars Baerfacker; Peter Eilbracht 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Synthesis of Heterofunctionalised Diamin

Synthesis of Heterofunctionalised Diamines and Triamines by Hydroaminomethylation of Diallyl Ethers, -silanes, or -amines

✍ Peter Eilbracht; Christian Ludger Kranemann; Lars Bärfacker 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 273 KB

Synthesis of Heterofunctionalised Diamines and Triamines by Hydroaminomethylation of Diallyl

ChemInform Abstract: Synthesis of Hetero

ChemInform Abstract: Synthesis of Heterofunctionalized Diamines and Triamines by Hydroaminomethylation of Diallyl Ethers, -silanes, or -amines.

✍ Peter Eilbracht; Christian Ludger Kranemann; Lars Baerfacker 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

ChemInform Abstract: New Silane Reductio

ChemInform Abstract: New Silane Reduction of Aromatic Ketones Mediated by Titanium Tetrachloride: A Synthesis of γ- and δ-Aryl Substituted Amino Acids.

✍ Michihisa Yato; Koichi Homma; Akihiko Ishida 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

Stereoselective Synthesis of Substituted

Stereoselective Synthesis of Substituted Cyclic Ethers and Amines by Acid-Catalyzed Cyclization of Vinylsilanes Bearing a Hydroxy or Amino Group

✍ Katsukiyo Miura; Akira Hosomi 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 53 KB 👁 1 views

One-Pot Synthesis of γ,δ-Unsaturated Car

One-Pot Synthesis of γ,δ-Unsaturated Carbonyl Compounds from Allyl Alcohols and Vinyl or Isopropenyl Acetates Catalyzed by [IrCl(cod)]2.

✍ Masao Morita; Satoshi Sakaguchi; Yasutaka Ishii 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 22 KB 👁 1 views