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Synthesis of Heterofunctionalised Diamines and Triamines by Hydroaminomethylation of Diallyl Ethers, -silanes, or -amines

✍ Scribed by Peter Eilbracht; Christian Ludger Kranemann; Lars Bärfacker


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
273 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis


Synthesis of Heterofunctionalised Diamines and Triamines by Hydroaminomethylation of Diallyl


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Heterofunctionalised allylic ethers 1, silanes 5, and amines 9 subsequent reductive amination to generate the corresponding functionalised secondary or tertiary amines. are hydroformylated in the presence of primary or secondary amines 2 to form the corresponding γ-amino-and δ-amino-This selective o