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Synthesis of β,γ-unsaturated ketones. A novel reaction of methyl lithium with β,γ-unsaturated carboxylic acids

✍ Scribed by J.Christopher Dalton; Hak-Foon Chan

Book ID
108381518
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
252 KB
Volume
14
Category
Article
ISSN
0040-4039

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Formation of a rearranged β,γ-enone from
Formation of a rearranged β,γ-enone from reaction of an acyclic β,γ-unsaturated carboxylic acid with methyl lithium
✍ J.Christopher Dalton; Bruce G. Stokes 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 209 KB

We have recently reported that reaction of B,y-unsaturated carboxylic acid 15 with methyl lithium yields, afterwork-up, unrearranged B,y-unsaturated ketone 25 in hexane and rearranged B,y-unsaturated ketone 3a in ether (eqn. l).' For-\_., mation of rearranged enone 3a in ether was rationalized by th