𝔖 Bobbio Scriptorium
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Synthesis of β-Aminophosphonates and -Phosphinates

✍ Scribed by Francisco Palacios; Concepcion Alonso; Jesus de los Santos


Book ID
101977658
Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✍ A Atmani; J.-C Combret; C Malhiac; J.Kajima Mulengi 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 105 KB

Vinylogous iminium salts from g-aminoenamines react with triethylphosphite to aord amino phosphonates in moderate to good yields. The latter are easily converted to a-substituted aminoallylphosphonates that can yield a-substituted aminoallylphosphonates on reaction with butyllitium and a series of e