A simple method of β-aminophosphonates synthesis
✍ Scribed by E. V. Grishkun; O. I. Kolodyazhnyi
- Book ID
- 111757854
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 131 KB
- Volume
- 79
- Category
- Article
- ISSN
- 1070-3632
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Vinylogous iminium salts from g-aminoenamines react with triethylphosphite to aord amino phosphonates in moderate to good yields. The latter are easily converted to a-substituted aminoallylphosphonates that can yield a-substituted aminoallylphosphonates on reaction with butyllitium and a series of e
The gold(I) catalyzed aldol reaction of diethyl a-isocyanomethylphosphonate with benzaldeyde gave the oxazoline 3, a P-hydroxy-a-aminophosphonic acid precursor, with high enantioand diastereoselectivity (98 % tram, 85 % ee) by employing a chiral ferrocenylamine ligand. The use of 31P NMR spectroscop