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Synthesis of Zirconium, Hafnium, and Tantalum Complexes with Sterically Demanding Hydrazide Ligands

✍ Scribed by Lehn, Jean-Sébastien M.; Javed, Saba; Hoffman, David M.

Book ID
125960716
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
134 KB
Volume
46
Category
Article
ISSN
0020-1669

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✍ Scollard, John D.; McConville, David H.; Vittal, Jagadese J. 📂 Article 📅 1995 🏛 American Chemical Society 🌐 English ⚖ 399 KB

The chelating diamide complexes (BDAPIZr-(NMed2 (21, (BDAP)ZrClz(pyh (4), (BDAP)ZrR2 (5a, R = CH2Ph; 5b, R = Me), (BDAP) Zr(l;15-Cp)C1 (5c), and(BDAP)Zr(rl2(N,C)-NC5H4)(CH2CMe2Ph) (5d) (BDAP = ArNCH2CH2CHJLAr; Ar = 2,6-iPr~-Cd-€3) have been prepared. An X-ray study of (BDAP)Zrf$(N,C)-NC5H4)-( CH2CMe