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Synthesis of well-defined polystyrene by radical polymerization using 1,1,2,2-tetraphenyl-1,2-ethanediol/feCl3/PPh3 initiation system

โœ Scribed by Xiao-Ping Chen; Kun-Yuan Qiu


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
145 KB
Volume
77
Category
Article
ISSN
0021-8995

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Radical polymerization of 2-, 3-, and 4-chlorostyrenes (ClSts) was investigated with benzoyl peroxide (BPO) as an initiator, in the presence of 4-methoxy-2,2,6,6tetramethylpiperidine-1-oxyl (MTEMPO). The polymerization was performed in bulk for 3.5 h at 95ะŠC and then continued for a defined time at