Synthesis of Well-Defined Poly(methyl methacrylate) by Radical Polymerization with a New Initiation System TPED † /FeCl 3 /PPh 3
✍ Scribed by Chen, Xiao-Ping; Qiu, Kun-Yuan
- Book ID
- 121867297
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 102 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The living/controlled radical polymerization of styrene was investigated with a new initiating system, DCDPS/FeCl 3 /PPh 3 , in which diethyl 2,3-dicyano-2,3diphenylsuccinate (DCDPS) was a hexa-substituted ethane thermal iniferter. The polymerization mechanism belonged to a reverse atom transfer rad
## Abstract Cuprous __N__,__N__‐Diethyldithiocarbamate, Cu(S~2~CNEt~2~), was successfully used as a catalyst in __p__‐toluenesulfonyl chloride initiating atom‐transfer radical polymerization of methyl methacrylate in both bulk and solution in a heterogeneous system with 2,2′‐bipyridine as the ligan