## Abstract Graft copolymerization of vinyl monomers onto chitosan and other natural polymers using atom transfer radical polymerization has only recently attracted interest. This technique could potentially provide new ways to utilize this abundant natural polymer. It would enable a wide variety o
Synthesis of well-defined poly(alkyl methacrylate)-graft-polylactone by sequential living polymerization
✍ Scribed by David Mecerreyes; Philippe Dubois; Robert Jérôme; James L. Hedrick
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 115 KB
- Volume
- 200
- Category
- Article
- ISSN
- 1022-1352
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The `living' radical polymerization of 2-(2',3',4',6'-tetra-O-acetyl-b-D-glucopyranosyloxy)ethyl acrylate (AcGEA) by atom transfer radical polymerization (ATRP) is reported. It has been found that the polymerization kinetics are ®rst-order, the molecular weights increase linearly with conversion, an