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Synthesis of vinylic and cyclic sulfones via a radical addition-elimination sequence

✍ Scribed by Albert Padwa; S.Shaun Murphree; Philip E. Yeske

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
253 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

Radical attack on the double bond of 2,3-bis(phenylsulfonyl)-1 -propene leads to an intermediate sulfonyl stabilized radical. This species readily fragments to produce a new vinyl sulfone which can undergo further radical cyclization to give a six ring sulfone.

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