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Synthesis of vinylcyclopropanes by intramolecular epoxide ring opening. Application for an enantioselective synthesis of dictyopterene A

โœ Scribed by Narjes, Frank; Bolte, Oliver; Icheln, Detlef; Koenig, Wilfried A.; Schaumann, Ernst

Book ID
126889064
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
950 KB
Volume
58
Category
Article
ISSN
0022-3263

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โœ Olga A Ozhogina ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 72 KB

The syntheses of nitroxyl oxirane and further functionalized derivatives are described. Ring-cleavage reactions of this epoxide have been carried out with a variety of nucleophiles in order to show the general synthetic utility for preparing nitroxyls bearing two functional groups. The relatively fa