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Synthesis of unsymmetrically substituted TTF derivatives via the “phosphonate way”. Some investigations on the scope of the method

✍ Scribed by H.J. Cristau; F. Darviche; M.-T. Babonneau; J.-M. Fabre; E. Torreilles

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
482 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis

The scope and limitations of the .synthesis of tmsymmetricaily substituted TIT derivatives via the "'phosphonate way" was investigated using as precursors 1.3-dithiol-2-yl-phosphonates and 1.3-dithiol-2-yliden iminium salts with various substituents on the dithiole cycles. Except for the un-or monosubstituted phosphonates, the one-pot procedure proves to be general and affords in all cases a significant improvement in the overall yields in TIT derivatives. The study has shown also that the formation of the intermediate adducts occurs in high yield, but their transformation into TIT derivatives, in presence of anhydrous acetic acid, is strongly sensitive to the nature of the various substituents, particularly on the iminium part

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