Synthesis of two fragments of the 14-membered macrolide antibiotic oleandomycin from D-glucose
β Scribed by Costa, Sonia Soares; Olesker, Alain; Ton That Thang, ; Lukacs, Gabor
- Book ID
- 118043799
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 560 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The C,-C6 segment of a number of 14-membered macrolide antibiotics have been synthesized started from levoglucosan.
D-Glucose was converted to a backbone chain containing the appropriate functionalities an correc7 stereochemistry for the construction of the Cl-C9 fragment of the 16-membered ring macrolide antibiotics carknycin A and B and leuccqzin A3. Ieucctnycin AS and carkmycins A and B (magnamycins A and B) s
A highly stereoselective and efficient synthesis of methynolide, the aglycone of 12membered macrolide methymycin, was achieved from of Cl-C8 and C9-Cl3 segments synthesized from D-glucose by employing some stereoselective reactions and benzyl-type protecting groups.