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Synthesis of tritiated derivatives of the diphenylether herbicides acifluorfen and acifluorfen methyl

✍ Scribed by René Mornet; Lucien Gouin; Michel Matringe; René Scalla; Colin Swithenbank

Book ID
102375819
Publisher
John Wiley and Sons
Year
1992
Tongue
French
Weight
336 KB
Volume
31
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Acifluorfen 1 and acifluorfen methyl 2, two herbicides of the diphenylether family, are inhibitors of protoporphyrinogen oxidases. Two tritiated derivatives of these compounds, namely 3‐[^3^H]‐5‐[2‐chloro‐4‐(trifluoromethyl)phenoxy]‐2‐nitrobenzoic acid [^3^H]‐1, and methyl 3‐[^3^H]‐5‐[2‐chloro‐4‐(trifluoromethyl)phenoxy]‐2‐nitrobenzoic acid [^3^H]‐2, have been synthesised from 3‐[^3^H]‐5‐hydroxybenzoic acid, in order to probe their interactions with the target enzymes.

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