Synthesis of Tris(dimethylphosphonium bismethylide)chromium(III)
✍ Scribed by Dr. habil. Erhard Kurras; Dipl.-Chem. Uwe Rosenthal; Dr. Herbert Mennenga; Dr. Günther Oehme
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 220 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Tris(2′‐[2‐phenyl‐1,3‐dioxolano])chromium(III) **3** has been synthesised and has been shown to have the __cis__ (or __fac__) configuration **3a** by X‐ray analysis: the CrC bond length is 2.037 (10) Å.
Refinement of the Superstructure of C-Type Chromium(III) Tris( metaphosphate), Cr(PO3)3. -Single crystals of Cr(PO3)3 are obtained during irreversible transport experiments starting with CrPO4, P and I (1323 → 1223 K, Si ampoule). The compound (monoclinic, Cc, Z = 12), which belongs to the M(PO3)3 p