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Synthesis of Tris(dimethylphosphonium bismethylide)chromium(III)

✍ Scribed by Dr. habil. Erhard Kurras; Dipl.-Chem. Uwe Rosenthal; Dr. Herbert Mennenga; Dr. Günther Oehme


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
220 KB
Volume
12
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Synthesis and Structure of Tris (2′-[2-p
✍ John J. Daly; Francisco Sanz; Raymond P. A. Sneeden; Harold H. Zeiss 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 203 KB

## Abstract Tris(2′‐[2‐phenyl‐1,3‐dioxolano])chromium(III) **3** has been synthesised and has been shown to have the __cis__ (or __fac__) configuration **3a** by X‐ray analysis: the CrC bond length is 2.037 (10) Å.

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Refinement of the Superstructure of C-Type Chromium(III) Tris( metaphosphate), Cr(PO3)3. -Single crystals of Cr(PO3)3 are obtained during irreversible transport experiments starting with CrPO4, P and I (1323 → 1223 K, Si ampoule). The compound (monoclinic, Cc, Z = 12), which belongs to the M(PO3)3 p