The synthesis and characterization of metal polyyne polymers containing disilane, disiloxane and phosphine groups in the main chain are described. The platinum and palladium poly-yne polymers were synthesized by polycondensation reactions between a metal chloride and an a, w-bisethynyl complex in am
✦ LIBER ✦
Synthesis of transition metal–poly(yne) polymer possessing chiral acetylene bridges
✍ Scribed by Onitsuka, Kiyotaka; Harada, Yuri; Takei, Fumie; Takahashi, Shigetoshi
- Book ID
- 120029984
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 52 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1359-7345
- DOI
- 10.1039/A800372F
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## Abstract The first examples of poly(ferrocenylsilane)‐poly(carbosilane) random copolymers have been prepared via the transition metal‐catalyzed ring‐opening copolymerization of silicon‐bridged [1]ferrocenophanes and disila‐ or benzosilacyclobutane.