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Transition metal-catalyzed ring-opening copolymerization of silicon-bridged [1]ferrocenophanes and sila- or disilacyclobutanes: Synthesis of poly(ferrocenylsilane)-poly(carbosilane) random copolymers

✍ Scribed by John B. Sheridan; Paloma Gómez Elipe; Ian Manners

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 293 KB
Volume: 17
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.1996.030170506

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✦ Synopsis

Abstract

The first examples of poly(ferrocenylsilane)‐poly(carbosilane) random copolymers have been prepared via the transition metal‐catalyzed ring‐opening copolymerization of silicon‐bridged [1]ferrocenophanes and disila‐ or benzosilacyclobutane.

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Transition Metal-Catalyzed Ring-Opening

Transition Metal-Catalyzed Ring-Opening Polymerization of Silicon-Bridged [1]Ferrocenophanes in the Presence of Functional Silanes: Molecular Weight Control and Synthesis of Telechelic Poly(ferrocenylsilanes)

✍ Alexandra Bartole-Scott; Rui Resendes; Ian Manners 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract The transition metal‐catalyzed ring‐opening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fc = Fe(__η__‐C~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^