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Synthesis of thione S-imides by alkylidenation of sulfinylanilines and imination of sulfines

โœ Scribed by Porskamp, Pascal A. T. W.; Zwanenburg, Binne

Book ID
120373157
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
517 KB
Volume
48
Category
Article
ISSN
0022-3263

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The synthesis and chemical properties of ylidenesulfimides (thione S-imides, X=S=N-), a novel type of thiocumulene, have recently been investigated! For example, fluorenethione S-tosylimides react not only as a 4s-system (1,3dipoles, enophiles) but also as a 28-system (dienophiles) in cycloaddition