Synthesis of sulfines by an alkylidenation of sulfur dioxide using α-silyl carbanions
✍ Scribed by M. van der Leij; P.A.T.W. Porskamp; B.H.M. Lammerink; B. Zwanenburg
- Book ID
- 108384567
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 183 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Several routes are reported for the synthesis of sulfines (thione Soxides), uiz. dehydrohalogenation of appropriately substituted sulfinyl 2 chlorides
Synthetically valuable cc-alkylidene-B-lactams are produced from the addition of chlorosulfonyl isocyanate to allenyl sulfides. Recently, several cr-alkylidene-B-lactams have been shown to be potent B-lactamase inhibitors. Included are the asparenomycins' (l), Ro 15-1903' (Z), and 6-r(L)-methoxymeth
Treatment of magnesium alkylidene carbenoids, which were generated from 1-chlorovinyl p-tolyl sulfoxides with a Grignard reagent by sulfoxide-magnesium exchange, with lithium a-sulfonyl carbanions gave allenes in moderate to good yields. This procedure offers a novel synthetic method for allenes wit