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Synthesis of Thioglycosides by Tetrathiomolybdate-Mediated Michael Additions of Masked Thiolates.

✍ Scribed by Perali Ramu Sridhar; Kandikere Ramaiah Prabhu; Srinivasan Chandrasekaran


Publisher
John Wiley and Sons
Year
2005
Weight
37 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Diastereoselective reactions of suitably functionalized homochiral I~-iminosulfoxides with Michael acceptors provide a new and efficient route for the asymmetric synthesis of C-4 substituted 2-pyroaminoadipates. Extension of the scope of the sulfoxide-mediated aza-enolate conjugate addition (Hua's r