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Novel Michael addition promoted by tributylstannylcarbamate. Synthesis of diacylcyclopropanes

✍ Scribed by Ikuya Shibata; Yoshiyuki Mori; Hayahide Yamasaki; Akio Baba; Haruo Matsuda


Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
240 KB
Volume
34
Category
Article
ISSN
0040-4039

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Active Template Synthesis of Rotaxanes a
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Scheme 1. Synthesis of metal-coordinated [2]rotaxane [(L3)Pd] by an active template Pd II -promoted double Michael addition, and its decomplexation to hydrogen-bonded molecular shuttle H 2 L3. a) DIPEA, CH 2 Cl 2 (see Table 1 for the effects of reagent stoichiometry on the yield of rotaxane [(L3)Pd]

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✍ Stephen M. Goldup; David A. Leigh; Paul J. Lusby; Roy T. McBurney; Alexandra M.  📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 595 KB

Scheme 1. Synthesis of metal-coordinated [2]rotaxane [(L3)Pd] by an active template Pd II -promoted double Michael addition, and its decomplexation to hydrogen-bonded molecular shuttle H 2 L3. a) DIPEA, CH 2 Cl 2 (see Table 1 for the effects of reagent stoichiometry on the yield of rotaxane [(L3)Pd]