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Synthesis of the Tetraketide Lactones from the Pikromycin Biosynthetic Pathway

✍ Scribed by Hong-Se Oh; Ji-Suk Yun; Ki-Hyun Nah; Han-Young Kang; David H. Sherman

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
235 KB
Volume
2007
Category
Article
ISSN
1434-193X

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## Abstract A fast and efficient route to ^32^P‐labeled intermediates on the purine biosynthetic pathway is described. Adenosine kinase catalyzes the phosphorylation of 5‐aminoimidazole‐4‐carboxamide ribonucleoside (AICARs) to give [^32^P]‐5‐aminoimidazole‐4‐carboxamide ribonucleotide (AICAR). This