Synthesis of the Star-Shaped Copolymer of ε-Caprolactone and l -Lactide from a Cyclotriphosphazene Core
✍ Scribed by Cui, Yanjun; Tang, Xiaozhen; Huang, Xiaobin; Chen, Yan
- Book ID
- 126075378
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 57 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1525-7797
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Biodegradable and photocurable block copolymers of __ε__‐caprolactone and L‐lactide were synthesized by polycondensation of PLLA diol ($\overline {M} \_{{\rm n}} $ = 10 000 g · mol^−1^), PCL diol ($\overline {M} \_{{\rm n}} $ = 10 000 g · mol^−1^), and a chain extender bearing a coumari
## Abstract **Summary:** Well‐defined star‐shaped poly(__ε__‐caprolactone)‐__b__‐poly(L‐lactide) copolymers (PCL‐__b__‐PLLA) were synthesized via sequential block copolymerization, and their molecular weights and arm length ratio could be accurately controlled. Both differential scanning calorimetr
## Abstract Hexaarmed star‐shaped hydroxyl‐terminated poly(ε‐caprolactone) (PCL) was successfully synthesized via the ring‐opening polymerization of ε‐caprolactone (CL) with hexakis[__p__‐(hydroxymethyl)phenoxy]cyclotriphosphazene initiator and stannous octoate catalyst in bulk. The star‐shaped PCL