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Synthesis of the Polyketomycin Disaccharide (I).

✍ Scribed by Douglas S. Micalizzi; J. Patrick Dougherty; Lincoln A. Noecker; Garry R. Smith; Robert M. Giuliano


Publisher
John Wiley and Sons
Year
2004
Weight
65 KB
Volume
35
Category
Article
ISSN
0931-7597

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Direct Synthesis of Pseudo-Disaccharides
✍ Alan James Pearce; Matthieu Sollogoub; Jean-Maurice Mallet; Pierre SinaΓΏ πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 520 KB

The series of unsaturated disaccharides 10-14 undergo (triisobutylaluminium) to afford (1Ǟ4) and (1Ǟ6) etherlinked pseudo-disaccharides 2-9. stereoselective reductive rearrangement with TIBAL to afford substituted cyclohexane derivatives with retention