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Synthesis of the Phosphoramidite Derivative of 2‘-Deoxy-2‘ -C- β-methylcytidine

✍ Scribed by Li, Nan-Sheng; Piccirilli, Joseph A.

Book ID
125807223
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
84 KB
Volume
68
Category
Article
ISSN
0022-3263

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✍ Gerardo Caballero; Mariana Gallo; Javier M. Montserrat; Adolfo M. Iribarren 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 154 KB 👁 2 views

We describe the stereoselective synthesis of (2'S)-2'-deoxy-2'-C-methyladenosine ( ) and (2'S)-2'-deoxy-2'-C-methylinosine ( ) as well as their corresponding cyanoethyl phosphoramidites 16 and 19 from 6-O-(2,6dichlorophenyl)inosine as starting material. The methyl group at the 2'-position was introd