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Synthesis of the pentasaccharide hapten from the glycopeptidolipid antigen of Mycobacterium avium serovar 17
✍ Scribed by Zsolt Varga; István Bajza; Gyula Batta; András Lipták
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 118 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Effective synthesis of the pentasaccharide hapten from the glycopeptidolipid antigen of Mycobacterium avium serovar 17 in a p-aminophenyl linker-containing form, using 3+2 block synthesis strategy, is described. A 2+3 block synthesis could not be achieved, although different glycosyl donors (1-Br, 1-SPh, 1-O-C(NH)CCl 3 ) were used.
📜 SIMILAR VOLUMES
An effective synthesis of the pentasaccharide hapten from the glycopeptidolipid antigen of Mycobacterium avium serovar 12 in the protected p-nitrophenyl glycoside, using a 3+2 block synthesis strategy, is described.
aujaceni ~noiecuie oi I . I nis close approacn 01 iwo molecules of 1 is shown in Figure 3. The three benzene solvent molecules in 1, however, do not adopt positions that place their flat surfaces in contact with the C,, unit. These benzene molecules are merely occupying what would otherwise be voids