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Synthesis of the N -((1 E )-Alkenyl)-(2 Z ,4 Z )-heptadienamide Side Chain of Salicylihalamide A and Apicularens A and B

โœ Scribed by Snider, Barry B.; Song, Fengbin

Book ID
127134124
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
73 KB
Volume
2
Category
Article
ISSN
1523-7060

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A stereospecific synthesis of conjugated
A stereospecific synthesis of conjugated (E,Z)-and (E,E)-alkadienes by the palladium-catalyzed reaction of (E)-1-alkenylboronic acids and 1-alkenyl iodides
โœ G. Cassani; P. Massardo; P. Piccardi ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

The reaction of (E)-1-alkenylboronic acids with (Z)-or(E)-1-alkenyl iodides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and sodium hydroxide gave the corresponding conjugated (E,E)-or (E,E)--alkadienes with high stereospecificity. Cross-coupling reactions between 1