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A highly stereoselective synthesis of 2(S), 3(R), 4E- and 2(S), 3(R), 4Z-N-tetracosanoylsphingenine from d-glucose

โœ Scribed by Katsuya Koike; Masaaki Numata; Mamoru Sugimoto; Yoshiaki Nakahara; Tomoya Ogawa


Book ID
107725576
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
798 KB
Volume
158
Category
Article
ISSN
0008-6215

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Stereoselective synthesis of (2S,3S,4R,5
โœ Makoto Oba; Tsutomu Terauchi; Jun Hashimoto; Tomohiro Tanaka; Kozaburo Nishiyama ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 227 KB

A catalytic deuteration of protected 3,4-dehydro-L-proline using RuCI2(PPh3) 3 followed by RuO~-oxidation gave a 3,4-dideuterated L-pyroglutamic acid derivative which is considered to be a promising precursor for various deuterated amino acids. The present study demonstrates a stereoselective reduct