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Synthesis of the Isolable Biradicals • (CH 3 B) 11 C−C⋮C−C(BCH 3 ) 11• and trans- • (CH 3 B) 11 C−CHCH−C(BCH 3 ) 11•

✍ Scribed by Eriksson, Ludvig; Vyakaranam, Kamesh; Ludvík, Jiří; Michl, Josef


Book ID
124154808
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
159 KB
Volume
72
Category
Article
ISSN
0022-3263

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11B13C coupling constant in LiB(CH3)4
✍ Masaru Yanagisawa; Osamu Yamamoto 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 170 KB

## Abstract Coupling constants between ^11^B and ^13^C, ^13^C and ^1^H, and ^11^B and ^1^H were obtained for LiB(CH~3~)~4~ in 1,2‐dimethoxyethane, in which the anion B(CH~3~) is belived to exist as a separate ion pair. The correlations of the coupling constants with the effective nuclear charge of