𝔖 Bobbio Scriptorium
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Synthesis of the heptapeptide of the cyclopeptide moiety of polymixin B

✍ Scribed by E. A. Morozova; M. A. Zevail'

Book ID
112373647
Publisher
Springer
Year
1970
Tongue
English
Weight
140 KB
Volume
6
Category
Article
ISSN
0009-3130

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πŸ“œ SIMILAR VOLUMES

Approach towards the total synthesis of
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✍ Taoues LaΓ―b; Jieping Zhu πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 243 KB

Macrocylization via formation of aryl-alkyl ether bond was a key step in a model synthesis of 14-membered cyclopeptide alkaloids. A new chemoenzymadc synthesis of chiral 2amino-l-arylethanol was developed in the course of this study

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A total synthesis of the proposed structure 1 for cyclodidemnamide from the marine ascidian Didemnum molle is described, which features the novel double, sequential formation of chiral thiazoline and oxazoline rings as the key stratagem.