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Synthesis of the Geometric Isomers of the 1,2,4-trimethylcyclohexanes

✍ Scribed by Bahram H. Mahmoud


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
445 KB
Volume
37
Category
Article
ISSN
1615-4150

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Synthesis of deuterated methyl 6,9,12-oc
✍ Henry Rakoff πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 402 KB

15, 16, 16.d 4 and the corresponding eis.cis, trans isomer were obtained by coupling hexyl-d~-triphenylphosphonium bromide and methyl 12-oxo-cis-6,cis-9-dodecadienoate by the Wittig reaction. The deuterated phosphonium salt was prepared from 3-hexynol by catalytic deuteration of the corresponding