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Synthesis of the EF-Ring of Ciguatoxin 3C Based on the [2,3]-Wittig Rearrangement and Ring-Closing Olefin Metathesis

✍ Scribed by Goto, Akiyoshi; Fujiwara, Kenshu; Kawai, Ayako; Kawai, Hidetoshi; Suzuki, Takanori


Book ID
125940886
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
118 KB
Volume
9
Category
Article
ISSN
1523-7060

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Armatol F, isolated from the red alga Chondria armata as a polyether triterpene, has a fused tricyclic ether moiety (BCD-ring) with an unusual cis ring junction at C18-C19 between the C-and D-rings. En route to the total synthesis of armatol F, the stereoselective construction of the C18 and C19 ste