An Ireland–Claisen rearrangement/RCM based approach for the construction of the EF-ring of ciguatoxin 3C
✍ Scribed by Nogoshi, Keisuke; Domon, Daisuke; Fujiwara, Kenshu; Kawamura, Natsumi; Katoono, Ryo; Kawai, Hidetoshi; Suzuki, Takanori
- Book ID
- 118232419
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- French
- Weight
- 856 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Armatol F, isolated from the red alga Chondria armata as a polyether triterpene, has a fused tricyclic ether moiety (BCD-ring) with an unusual cis ring junction at C18-C19 between the C-and D-rings. En route to the total synthesis of armatol F, the stereoselective construction of the C18 and C19 ste
Ireland-Cl&en rearrangement of the ester 21 gave 22 with the correct C3 stereochemistry.
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