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Synthesis of the C(19)C(32) fragment of scytophycin C via stereospecific methylation of γ,δ-epoxy acrylates with trimethylaluminum

✍ Scribed by Paul A. Grieco; Jason D. Speake; Sin Koo Yeo; Masaaki Miyashita

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
215 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of the C(19) -C(32) fragment of Scytophycin C is described which features an iterative, stereospecific methylation of y,8-epoxy acrylates by trimethylaluminum and the use of Roush's (S,S)diisopropyltartrate-E-crotylboronate.

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