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ChemInform Abstract: Synthesis of the C19—C32 Fragment of Scytophycin C via Stereospecific Methylation of γ,δ-Epoxy Acrylates with Trimethylaluminum.

✍ Scribed by P. A. GRIECO; J. D. SPEAKE; S. K. YEO; M. MIYASHITA

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of the C 19 -C 32 Fragment of Scytophycin C via Stereospecific Methylation of γ,δ-Epoxy Acrylates with Trimethylaluminum. -The synthesis of the title compound features an iterative, stereospecific methylation of γ,δ-epoxy acrylates (II) and (V) by trimethylaluminum in the presence of an excess of water. -(GRIECO, P. A.;

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