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Synthesis of the alkaloids julandine and ipalbidine-use of silicon (IV) chloride

✍ Scribed by John E Cragg; Stuart H Hedges; Richard B Herbert


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
153 KB
Volume
22
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


General methods of alkaloid synthesis. X
✍ Robert V. Stevens; Yuhshi Luh πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 178 KB

## Recently, we reported' the total synthesis of (*)-isoretronecanol (1) and (+)-8-coniceine (2). A key step in each of these syntheses utilized the acid-catalyzed rearrangement of a cyclopropylimine to generate the 3-phenylthio-2-pyrroline synthon (2). The latter intermediate serves as a relative