Synthesis of the 3-deoxy-3-C-(phosphonomethyl) analogue of 1d-myo-inositol 3-(dihydrogenphosphate)
β Scribed by Stephen C. Johnson; Frank Tagliaferri; David C. Baker
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 468 KB
- Volume
- 250
- Category
- Article
- ISSN
- 0008-6215
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β¦ Synopsis
93)E0230-X * Compound 2 may also be considered as lL-l-deoxyl-C-(phosphonomethyl)-myo-inositol.
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In the paper by G. Horne and B. V. L. Potter published in Chem. Eur. J. 2001, 7, 80, there is a mistake in the drawing of some regiochemistry of the structural diagrams in Schemes 1 Β± 3. The correct structures are given below.
Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose. -The key step in the synthesis of the title compounds is the Ferrier rearrangement of pyranoside (II). Both resulting cyclohexanones (III) and (IV) can be trans
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