Synthesis of tetrasubstituted acylaminophthalocyanines of cobalt
β Scribed by E. R. Milaeva; S. D. Kolnin; V. S. Petrosyan
- Book ID
- 112540112
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 187 KB
- Volume
- 45
- Category
- Article
- ISSN
- 1573-9171
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A versatile route for the synthesis of fi-lactones via oxidation of tetrasubstituted cyclopWanona is deseribed. Eachstepin thesyntbeticpatbway fromcis-2-oxabicyc3~3.3.O]ou-fi-en-2one to theketonesproceedswithexcellentregio-andstereoselectivity andin goodyield. Baeyer-Vi3tiger oxidationof tbe cyclope
For investigations concerning the selectivity of polyketide synthases (PKSs) which have been rationally engineered through genetic techniques the synthesis of substituted Slactones is of great importance. An enantiospecific route towards eight of the possible sixteen stereoisomers was developed whic