Lead(II)-selective PVC membrane electrodes based on 4,7,13,7,13, as ionophore were prepared. The optimum composition of the membrane was 30 wt% poly(vinyl chloride), 67 wt% 2-nitrophenyl octyl ether plasticizer, 3 wt% ionophore with added lipophilic salt potassium tetrakis( p-chlorophenyl)borate at
Synthesis of Tetra-N-substituted 1,10-dioxa-4,7,13,16- tetraazacyclooctadecanes and their Application as Lead (II) Selective Electrodes. X-ray Crystal Structure of 4,7,13,16-tetrathenoyl-1,10- dioxa-4,7,13,16-tetraazacyclooctadecane
β Scribed by Xinhao Yang; Donald C. Craig; Aresh Kumar; D. Brynn Hibbert
- Book ID
- 110258318
- Publisher
- Springer Netherlands
- Year
- 1999
- Tongue
- English
- Weight
- 84 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0923-0750
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A new crown ether derivative 4,7,13,16-tetrabenzyl-1,10-dioxa-4,7,13,16-tetraaza-cyclooctadecane together with its binuclear copper(II) complex have been prepared and characterized by elemental analysis, IR, NMR and UV spectra. X-ray diffraction study shows that the complex crystallizes in the monoc
## Abstract The molecular structures of the title compounds 3 and 5 were investigated by NMR and Xβray structural methods. The NMR results suggest two equivalent halves for both molecules. The Xβray study shows an approximate mirror plane for 3 and an approximate twofold axis for a significant port