Iridium carboxycarbene complexes by CH b
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Ernesto Carmona; Margarita Paneque; Laura L. Santos; Verónica Salazar
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Article
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2005
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Elsevier Science
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English
⚖ 454 KB
The double C H bond activation of ethers that have an alkyl terminus, RCH 2 OR (R = alkyl, aryl), is a useful route to heteroatom-stabilized iridium carbenes, Ir = C(R)OR . An overview of our recent work in this field, using Ir(III) fragments stabilized by hydrotris(pyrazolyl)borate ligands, is pres