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Iridium carboxycarbene complexes by CH bond activation of aliphatic ethers and of alkyl aryl ethers

✍ Scribed by Ernesto Carmona; Margarita Paneque; Laura L. Santos; Verónica Salazar


Book ID
104010759
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
454 KB
Volume
249
Category
Article
ISSN
0010-8545

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✦ Synopsis


The double C H bond activation of ethers that have an alkyl terminus, RCH 2 OR (R = alkyl, aryl), is a useful route to heteroatom-stabilized iridium carbenes, Ir = C(R)OR . An overview of our recent work in this field, using Ir(III) fragments stabilized by hydrotris(pyrazolyl)borate ligands, is presented concentrating on some aliphatic, non-cyclic ethers and on anisole, the latter taken as a representative example of alkyl aryl ethers.


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