Synthesis of terpene–poly(ethylene oxide)s by t-BuP4-promoted anionic ring-opening polymerization
✍ Scribed by Zhao, Junpeng; Schlaad, Helmut; Weidner, Steffen; Antonietti, Markus
- Book ID
- 115469287
- Publisher
- The Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 358 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1759-9954
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## Abstract The eight‐shaped poly(ethylene oxide) (PEO) is synthesized by a combination of Glaser coupling with ring‐opening polymerization (ROP). Firstly, the star‐shaped **(PEO‐OH)**~**4**~ is synthesized by ROP of ethylene oxide (EO) using pentaerythritol as an initiator and diphenylmethyl potas
## Abstract Model poly[ethylene‐__block__‐(L,L‐lactide)] (PE‐__block__‐PLA) block copolymers were successfully synthesized by combining metallocene catalyzed ethylene oligomerization with ring‐opening polymerization (ROP) of L,L‐lactide (LA). Hydroxy‐terminated polyethylene (PE‐OH) macroinitiator w